Articles | Volume 16, issue 2
https://doi.org/10.5194/os-16-535-2020
https://doi.org/10.5194/os-16-535-2020
Research article
 | 
27 Apr 2020
Research article |  | 27 Apr 2020

Impact of impurities in bromocresol green indicator dye on spectrophotometric total alkalinity measurements

Katharina Seelmann, Martha Gledhill, Steffen Aßmann, and Arne Körtzinger

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Cited articles

Aßmann, S., Frank, C., and Körtzinger, A.: Spectrophotometric high-precision seawater pH determination for use in underway measuring systems, Ocean Sci., 7, 597–607, https://doi.org/10.5194/os-7-597-2011, 2011. a
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Breland, J. A. and Byrne, R. H.: Spectrophotometric procedures for determination of sea water alkalinity using bromocresol green, Deep-Sea Res. Pt. I, 40, 629–641, https://doi.org/10.1016/0967-0637(93)90149-W, 1993. a, b, c
Byrne, R. H.: Standardization of standard buffers by visible spectrometry, Anal. Chem., 59, 1479–1481, https://doi.org/10.1021/ac00137a025, 1987. a
Byrne, R. H. and Breland, J. A.: High precision multiwavelength pH determinations in seawater using cresol red, Deep-Sea Res. Pt. I, 36, 803–810, https://doi.org/10.1016/0198-0149(89)90152-0, 1989. a
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Short summary
We investigated the impact of indicator dye impurities on spectrophotometric seawater measurements, especially how they may influence the drift behavior and the measurement quality of an autonomous analyzer using this indicator. These measurements are important for ocean carbon observations. This work revealed that impurities up to a quantity of 2 % do not influence the measurement drift and quality. Higher impurity levels lead to a changing drift behavior and quality deteriorations.